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Molecular tectonics: design of luminescent H-bonded molecular networks
Carmen Paraschiv1, Sylvie Ferlay, Mir Wais Hosseini
1Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, Strabourg, France.
Abstract:
Using bis-amidinium dications as tetra H-bond donor tectons and Au(CN)(2)(-) anion, neutral 1-D networks based on a bis monohapto mode of H-bonding are obtained. Owing to the short metal-metal distance within the network, luminescent crystals are obtained. The emission phenomena may be tuned by the nature of the spacer connecting the two cyclic amidinium groups.
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