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Updated: Aug 21, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Preparation and structural characterisation of terpy-cored dendrimers and dendriplexes
Edwin C Constable1, Catherine E Housecroft, Markus Neuburger
1Department of Chemistry, University of Basel, Spitalstrasse 51, CH 4056, Basel, Switzerland. edwin.constable@unibas.ch
Abstract:
2,2':6',2''-Terpyridine (terpy) ligands and their iron(II) and cobalt(II) complexes bearing first and second generation Frechet-type dendritic wedges have been prepared and structurally characterised. The rotational freedom within the dendritic wedge results in a great diversity in conformational space. Structural studies are reported on first generation species and their metal complexes, and the variety of inter- and intramolecular interactions which dominate the conformation of the dendrimer and the packing of the molecules (ions) in the lattice are discussed.
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