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Updated: Aug 9, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Structural anomalies and multiferroic behavior in magnetically frustrated TbMn2O5
L C Chapon1, G R Blake, M J Gutmann
1ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX, United Kingdom.
Abstract:
We have studied the magnetostructural phase diagram of multiferroic TbMn2O5 as a function of temperature and magnetic field by neutron diffraction. Dielectric and magnetic anomalies are found to be associated with steps in the magnetic propagation vector, including a rare example of a commensurate-incommensurate transition on cooling below 24 K, and in the structural parameters. The geometrically frustrated magnetic structure is stabilized by "canted antiferroelectric" displacements of the Mn3+ ions, an example of the magnetic Jahn-Teller effect. The Tb moments order ferromagnetically at low temperatures in an applied field, while the Mn magnetic structure is largely unchanged.
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