Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

1.8K
The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
1.8K
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

2.2K
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
2.2K
Thermal Electrocyclic Reactions: Stereochemistry01:17

Thermal Electrocyclic Reactions: Stereochemistry

2.5K
The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
2.5K
Energy Diagrams, Transition States, and Intermediates02:13

Energy Diagrams, Transition States, and Intermediates

20.3K
Free-energy diagrams, or reaction coordinate diagrams, are graphs showing the energy changes that occur during a chemical reaction. The reaction coordinate represented on the horizontal axis shows how far the reaction has progressed structurally. Positions along the x-axis close to the reactants have structures resembling the reactants, while positions close to the products resemble the products.  Peaks on the energy diagram represent stable structures with measurable lifetimes, while...
20.3K
EDTA: Chemistry and Properties01:22

EDTA: Chemistry and Properties

3.3K
Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...
3.3K
Autoxidation of Ethers to Peroxides and Hydroperoxides02:23

Autoxidation of Ethers to Peroxides and Hydroperoxides

9.4K
Ethers represent a class of chemical compounds that become more dangerous with prolonged storage because they tend to form explosive peroxides when standing in the air. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly oxidize to form hydroperoxides and dialkyl peroxides.
9.4K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Quantitative analysis of colorimetric hydrogel/paper mini-disk arrays using a handheld Wi-Fi scanner.

The Analyst·2026
Same author

Combining the Pitcher and Lotus Plant: Supericephobic and Superhydrophobic Silicone Films.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)·2026
Same author

Ultrafast Dynamics of Porphyrins in the Condensed Phase:  II. Zinc Tetraphenylporphyrin<sup>†</sup>.

The journal of physical chemistry. A·2025
Same author

Clicking Fluorometric Probes on Micropatterned Glass Microfiber Filters for ppb-Level Copper Quantitation.

Analytical chemistry·2025
Same author

UV/Ozone-Assisted Covalent Bioconjugation on Graphene Tapes.

Langmuir : the ACS journal of surfaces and colloids·2025
Same author

Microscale quantitation of heavy metals by back-scattering interferometry in conjunction with photothermal effect using a single laser beam.

Talanta·2024

Related Experiment Videos

New chemistry on old CDs.

Hua-Zhong Yu1

  • 1Department of Chemistry, Simon Fraser University, Burnaby, British Columbia, Canada V5A 1S6. hzyu@sfu.ca

Chemical Communications (Cambridge, England)
|November 30, 2004
PubMed
Summary

Old compact discs (CDs) offer versatile applications in chemical research. Their components enable advanced material fabrication, electrochemical analysis, and cost-effective biomedical diagnostics.

Area of Science:

  • Materials Science
  • Analytical Chemistry
  • Biotechnology

Background:

  • Compact discs (CDs) possess unique material properties not fully exploited in scientific research.
  • The reflective metal film and grooved polycarbonate structure offer potential for novel applications.

Purpose of the Study:

  • To explore the utility of discarded compact discs (CDs) in modern chemical research.
  • To demonstrate the application of CD components in material science, electrochemistry, and biomedical diagnostics.

Main Methods:

  • Utilizing the metal reflective film of CDs for self-assembled monolayers (SAMs) and electrochemical analysis.
  • Employing the pre-grooved polycarbonate base for fabricating material micro/nanostructures.
  • Immobilizing biomolecules on CDs for integration with standard CD drives.

Related Experiment Videos

Main Results:

  • High-quality SAMs and reliable electrochemical analysis were achieved using CD reflective films.
  • Customized material micro/nanostructures were successfully fabricated on the CD polycarbonate base.
  • A cost-effective platform for point-of-care biomedical diagnosis and gene analysis was developed using immobilized biomolecules on CDs.

Conclusions:

  • Old compact discs (CDs) represent a sustainable and valuable resource for diverse chemical research applications.
  • CDs can be repurposed for advanced materials fabrication, electrochemical studies, and accessible biomedical diagnostic tools.