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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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A fluorinated selenide linker for solid-phase synthesis of n-pentenyl glycosides

Mickael Mogemark1, Linda Gustafsson, Christoffer Bengtsson

  • 1Organic Chemistry, Department of Chemistry, Umeå University, SE-901 87 Umeå, Sweden.

Organic Letters
|December 21, 2004
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.