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Updated: Aug 19, 2026

Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes
Published on: December 15, 2015
One teflon-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic
Angeles Monge1, Natalia Snejko, Enrique Gutiérrez-Puebla
1Instituto de Ciencia de Materiales de Madrid (CSIC) Cantoblanco, 28049 Madrid, Spain. amonge@icmm.csic.es
Abstract:
Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties.
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