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Preparation and crystallographic characterization of C60Cl24

Natalia B Shustova1, Alexey A Popov, Lev N Sidorov

  • 1Chemistry Department, Moscow State University, Leninskie Gory, 119992 Moscow, Russia.

Chemical Communications (Cambridge, England)
|March 10, 2005
PubMed

Abstract:

C60Cl24 has been synthesized by the chlorination of C60 with VCl4 or C60Br24 with SbCl5; the X-ray single crystal structure of C60Cl24.2Br2 confirmed the molecular T(h) symmetry in good agreement with the IR data and theoretical calculations.

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The chair conformation is the most stable form of cyclohexane due to the absence of angle and torsional strain. The absence of angle strain is a result of cyclohexane’s bond angle being very close to the ideal tetrahedral bond angle of 109.5° in its chair conformer. Similarly, the torsional strain is also absent owing to the perfectly staggered arrangement of bonds.
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this staggered...

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