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Dendrimer-encapsulated Pd nanoparticles as aqueous, room-temperature catalysts for the Stille reaction

Joaquin C Garcia-Martinez1, Raphael Lezutekong, Richard M Crooks

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012, USA.

Journal of the American Chemical Society
|April 7, 2005
PubMed

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...