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Updated: Jul 31, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
06:55

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level

Published on: September 26, 2016

A computational study of [2.2]cyclophanes.

Giovanni F Caramori1, Sérgio E Galembeck, Kenneth K Laali

  • 1Departamento de Química, FFCLRP, Universidade de São Paulo, 14040-901 Ribeirão Preto-São Paulo, Brazil.

The Journal of Organic Chemistry
|April 13, 2005
PubMed
Summary

This study computationally investigated isomeric [2.2]cyclophanes, revealing strain and pi-cloud repulsion dictate stability. Aromaticity is maintained despite structural distortions, with electronic density concentrated between rings.

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