Polarographic oxygen permeability measurement of silicone elastomer contact lens material

The flexible silicone elastomer is a contact lens material of substantial potential, primarily because of its high theoretical oxygen permeability (Dk). Review of the previous literature indicates some difficulty in precisely determining the Dk of the silicone elastomer, and quantification of this permeability value ranges from 50 to 340 x 10(-11) cm2 ml 02/sec ml mmHg by various techniques. (The exponential term 10(-11) and the units of Dk will be omitted hereafter in this text). We herein report use of the single-chamber polarographic technique, with edge and boundary corrections, to arrive at a value of 190 with a standard deviation (SD) of 79 for the Dk of one silicone elastomer contact lens material. The excessive SD suggests that an improved method to evaluate contact lens materials with Dk values in excess of 30-50 should be determined.