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(2-Hydroxyethyl)hydrazinium(2+) dichloride.

Günseli Turgut1, Metin Zora, Mustafa Odabaşoğlu

  • 1Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Kurupelit Samsun, Turkey. gturgut@omu.edu.tr

Acta Crystallographica. Section C, Crystal Structure Communications
|May 7, 2005
PubMed
Summary

The crystal structure of 2-hydroxyethylhydrazinium chloride was determined. This compound features hydrogen bonds that stabilize its molecular and crystal structures.

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Area of Science:

  • Crystallography
  • Solid-state chemistry
  • Hydrogen bonding

Background:

  • Understanding the hydrogen bonding in organic salts is crucial for predicting their physical properties.
  • The 2-hydroxyethylhydrazinium cation is a novel moiety whose structural characteristics are not well-documented.

Purpose of the Study:

  • To elucidate the crystal structure of 2-hydroxyethylhydrazinium dichloride.
  • To investigate the role of hydrogen bonding in stabilizing the molecular and crystal architecture.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the atomic arrangement.
  • Structural analysis focused on identifying hydrogen bonding interactions and their geometric parameters.

Main Results:

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  • The crystal structure consists of 2-hydroxyethylhydrazinium(2+) cations and chloride anions.
  • Extensive O-H...Cl and N-H...Cl hydrogen bonds were observed, forming a three-dimensional network.
  • All five hydrazinium hydrogen atoms participate in hydrogen bonding with chloride anions.

Conclusions:

  • The crystal packing is significantly stabilized by a network of intermolecular hydrogen bonds.
  • The observed hydrogen bonding patterns provide insights into the solid-state behavior of this compound.