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Updated: Aug 17, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Dilead(II) trimercury(II) tetraoxide chromate(VI), Pb2(Hg3O4)(CrO4)
Wilhelm Klein1, Jan Curda, Martin Jansen
1Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart, Germany.
Abstract:
Pb2(Hg3O4)(CrO4) consists of [CrO4]2- tetrahedra, linear O-Hg-O dumbbells and divalent Pb atoms in [3+5]-coordination. The HgO2 dumbbells are condensed into [Hg3O4]2- units and can be regarded as a section of the HgO structure. The [Hg3O4]2- complex anions are connected by interstitial Pb2+ ions, while the [CrO4]2- tetrahedra are isolated.
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