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Updated: Aug 17, 2026

Investigations on the Ga(III) Complex of EOB-DTPA and Its 68Ga Radiolabeled Analogue
Published on: August 17, 2016
Chloro[N,N'-ethylenediiminobis(acetylacetonato)]gallium(III)
Jason K Vohs1, Duston O Miller, Dan R Denomme
1Department of Chemistry, Central Michigan University, Mt Pleasant, MI 48859, USA.
Abstract:
In the title compound, [Ga(C12H18N2O2)Cl], the Ga atom is coordinated to a Cl atom and the two imine N and two enolate O atoms of the Schiff base ligand. The literature reveals few examples of a five-coordinate GaO2N2Cl environment, and only two where both the N and the O atoms are contained within the same ligand. This configuration has the effect of constraining the complex into a square-pyramidal geometry with less distortion than if formed by two or more ligands. The Ga-N and Ga-O distances are within the ranges expected for Ga-Schiff base derivatives. This compound is also the first group 13 complex containing the N,N'-ethylenebis(acetylacetoneimine) (acacen) ligand.
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