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Updated: Jan 10, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
On the Use of Ce[N(SiMe3)2]3(THF)n in Catalysis
Jonah P Stiel1, Joseph W Ziller1, William J Evans1
1Department of Chemistry, University of California Irvine, Irvine, California 92697, United States.
None:
A recent catalysis study claimed Ce[N(SiMe3)2]3(THF)3 as the starting material but later published a correction indicating the starting material was unsolvated Ce[N(SiMe3)2]3. We report here that there is another possibility in this cerium amide system that should be considered, particularly if the presence of THF would be a problem due to ring opening side reactions. Crystallization of Ce[N(SiMe3)2]3 from THF forms the THF adduct Ce[N(SiMe3)2]3(THF). The synthesis and structure of the monosolvate, as well as binding constant studies, are reported.
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