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Updated: Aug 17, 2026
11:27
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
[{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36-: a molecular quantum spin icosidodecahedron
Bogdan Botar1, Paul Kögerler, Craig L Hill
1Department of Chemistry, Emory University, Atlanta, GA 30322, USA. bbotar@emory.edu
Chemical Communications (Cambridge, England)
|June 22, 2005
Abstract:
Self-assembly of aqueous solutions of molybdate and vanadate under reducing, mildly acidic conditions results in a polyoxomolybdate-based {Mo72V30} cluster compound Na8K16(VO)(H2O)5[K10 subset{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20].150H2O, 1, a quantum spin-based Keplerate structure.
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