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Kadsuphilactones A and B, two new triterpene dilactones from kadsuraphilippinensis

Ya-Ching Shen1, Yu-Chi Lin, Michael Y Chiang

  • 1Department of Marine Resources, National Sun Yat-Sen University, Taiwan, Republic of China. ycshen@mail.nsysu.edu.tw

Organic Letters
|July 16, 2005
PubMed

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...