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Supramolecular self-assembly on a solid support: metal-directed complementarity.

Edwin C Constable1, Catherine E Housecroft, John N Lambert

  • 1Department of Chemistry, Spitalstrasse 51, CH-4056, Basel, Switzerland. edwin.constable@unibas.ch

Chemical Communications (Cambridge, England)
|July 20, 2005
PubMed
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Researchers created polymer-supported bipyridines as templates. These templates guided the assembly and metathesis of terpyridine strands, forming complementary polymer chains.

Area of Science:

  • Coordination Chemistry
  • Polymer Chemistry
  • Supramolecular Chemistry

Background:

  • 2,2'-bipyridines and 2,2':6',2''-terpyridines are important ligands in coordination chemistry.
  • Templated synthesis offers a route to complex macromolecular architectures.

Purpose of the Study:

  • To develop a method for synthesizing complementary poly-2,2':6',2''-terpyridine strands.
  • To utilize resin-immobilized templates for controlled polymer assembly.

Main Methods:

  • Preparation of resin-immobilized (poly)-2,2'-bipyridines.
  • Copper(II)-mediated assembly of alkene-functionalised 2,2':6',2''-terpyridines using the immobilized template.
  • Subsequent templated metathesis to form the complementary polymer strands.

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Main Results:

  • Successful preparation of resin-immobilized (poly)-2,2'-bipyridines.
  • Demonstration of copper(II)-mediated templated assembly of functionalized terpyridines.
  • Formation of complementary poly-2,2':6',2''-terpyridine strands via templated metathesis.

Conclusions:

  • Resin-immobilized (poly)-2,2'-bipyridines are effective templates for synthesizing complex polymer structures.
  • The templated metathesis approach provides a novel route to complementary poly-terpyridine systems.