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Syntheses and crystal structures of [Ag123S35(StBu)50] and [Ag344S124(StBu)96]

Dieter Fenske1, Christopher E Anson, Andreas Eichhöfer

  • 1Institut für Anorganische Chemie der Universität Karlsruhe, Germany. dieter.fenske@aoc1.uni-karlsruhe.de

Angewandte Chemie (International Ed. in English)
|July 30, 2005
PubMed
Abstract

No abstract available in PubMed .

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Ionic Crystal Structures02:42

Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...