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Updated: Aug 11, 2026

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
Published on: July 9, 2015
An allylstannane reagent on non-cross-linked polystyrene support
E J Enholm1, M E Gallagher, K M Moran
1Department of Chemistry, University of Florida, Gainesville, Florida 32611, USA. enholm@chem.ufl.edu
Abstract:
[reaction: see text] A new allylstannane reagent on non-cross-linked polystyrene was developed for the first time. This support differs markedly from standard cross-linked polymers because it is completely soluble in organic solvents; moreover, the reactions can be conveniently monitored directly by standard 1H NMR methods. The allylstannane underwent a free radical reaction with an alkyl halide to form a new allyl appendage. Tin byproducts can be easily recovered from cold methanol as white crystalline solids.
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