A comparative study of cluster-surface collisions: Molecular-dynamics simulations of (H2O)1000 and (SO2)1000

A classical molecular-dynamics study of (H2O)1000 and (SO2)1000 clusters impacting with velocities between 6 x 10(2) and 8 x 10(3) ms at normal incidence on a repulsive target is presented. Using the ratio of total kinetic energy to total binding energy of the cluster as a scaling parameter, a general description of the fragmentation dynamics as well as the final fragment size distributions is achieved for the different systems. With increasing ratio, the angular distribution of the emitted monomers rapidly shifts from isotropic to anisotropic. At the highest investigated velocities, a tendency to recover more isotropic distributions is observed. Comparable transient compression of the impacting cluster is reached, on the other hand, for the same, unscaled collision velocities in both systems. For both H2O and SO2 the obtained internal temperatures of the cluster fragments are found to be independent of impact energy and close to the boiling temperature of the respective systems.