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Updated: Aug 16, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
catena-Poly[[[2,4-dichloro-6-(pyridin-2-ylmethyliminomethyl)phenolato]copper(II)]-mu-thiocyanato]
1Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China. youzhonglu@yahoo.com.cn
Abstract:
The title complex, [Cu(C13H9Cl2N2O)(NCS)]n, is a novel thiocyanate-bridged polynuclear copper(II) compound. The CuII atom is five-coordinated in a square-pyramidal configuration, with one O and two N atoms of one Schiff base ligand and one terminal N atom of a bridging thiocyanate ligand defining the basal plane, and one terminal S atom of another bridging thiocyanate ligand occupying the axial position. The [2,4-dichloro-6-(pyridin-2-ylmethyliminomethyl)phenolato]copper(II) moieties are linked by the bridging thiocyanate ligands, forming polymeric chains running along the a axis.
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