Related Experiment Video
Updated: Aug 16, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
Published on: July 28, 2022
Di-mu-azido-bis{[1-(2-pyridylmethyliminomethyl)-2-naphtholato]zinc(II)}
1Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China. youzhonglu@yahoo.com.cn
Abstract:
The title compound, [Zn2(C17H13N2O)2(N3)2], is an azide-bridged dinuclear zinc(II) complex which has inversion symmetry. The ZnII atom is five-coordinated in a square-pyramidal configuration by one O and two N atoms of one Schiff base ligand [Zn-O=1.902 (2) A and Zn-N=1.938 (2) and 2.002 (2) A] and by one terminal N atom [Zn-N=1.985 (2) A] of a bridging azide ligand defining the basal plane, and by another terminal N atom of another bridging azide ligand [Zn-N=2.554 (2) A] occupying the apical position.
More Related Videos
Related Concept Videos
Aryldiazonium Salts to Azo Dyes: Diazo Coupling
Diazonium Group Substitution: –OH and –H
Diazonium Group Substitution with Halogens and Cyanide: Sandmeyer and Schiemann Reactions
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism

