Condensation of a vapor bubble in submicrometer container

Condensation of a spherically symmetric submicrometer size vapor bubble is studied using diffuse interface hydrodynamic model supplemented by the van der Waals equation of state with parameters characteristic for argon. The bubble, surrounded by liquid, is held in a container of constant volume with temperature of the wall kept fixed. The condensation is triggered by a sudden rise of the wall temperature. We find that in the same container and subjected to a similar increase of the wall temperature the condensation process is totally different from the opposite process of droplet evaporation. In particular, the rapid change of the wall temperature excites the wave, which hits the interface and compresses the bubble, leading to a considerable increase of the temperature inside. The condensation of the submicrometer size bubble takes tens of nanoseconds, whereas evaporation of the same size droplet lasts roughly 50 times longer. In contrast to evaporation the condensation process is hardly quasistationary.