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Updated: Aug 15, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Morphological control and molecular recognition by bis-urea hydrogen bonding in micelles of amphiphilic tri-block
Natalia Chebotareva1, Paul H H Bomans, Peter M Frederik
1Eindhoven University of Technology, Department of Chemical Engineering, Macromolecular and Organic Chemistry, PO 513, 5600 MB, Eindhoven, The Netherlands.
Abstract:
Hydrogen bonding between urea groups of amphiphilic tri-block copolymers considerably affects their self-assembly in water, which results in a strong modification of morphology and viscosity of aqueous solutions; the hydrogen bonding motif in these amphiphilic copolymers allows molecular recognition of small molecules with complementary hydrogen bonding units.
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