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Near-infrared spectrophotometric determination of compositions of fullerene samples
Chieu D Tran1, Victor I Grishko, Santhosh Challa
1Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, WI 53201, USA. chieu.tran@marquette.edu
Abstract:
A novel method has been developed for the sensitive and accurate determination of compositions of fullerene samples. The method is based on the synergistic use of spectrophotometric measurements and partial least square method. The method is not only simple, inexpensive and fast but also is non-destructive. Compositions of various fullerene samples including fullerite which is the precursor to C(60) and C(70), can be directly and non-destructively determined by this method without any time-consuming separation step as in the HPLC method or destruction as in the MS method.
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