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Predictions, synthetic strategy, and isolation of a linear tetrametallic triple-stranded lanthanide helicate

Kornelia Zeckert1, Josef Hamacek, Jean-Michel Senegas

  • 1Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Switzerland.

Angewandte Chemie (International Ed. in English)
|November 18, 2005
PubMed
Abstract

No abstract available in PubMed .

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...