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Updated: Aug 14, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from
Jianghua He1, Jihong Yu, Yuetao Zhang
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China.
Abstract:
A new heterometallic MOF compound, [ZnNa(m-BDC)2].NH2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a=13.277(6) A, b=14.323(7) A, c=11.328(6) A, and beta=111.73(2) degrees. Its framework is constructed from M-O-C (M=Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.
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