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Updated: Aug 14, 2026

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
Monte Carlo simulation of the electrical differential capacitance of a double electrical layer formed at the
1Group for Theoretical Problems of Adsorption, Institute of Catalysis and Surface Chemistry, Polish Academy of Science, Krakow, Poland. piotrek@vega.umcs.lublin.pl
Abstract:
A semiempirical simulation study of differential capacitance c(d) is presented for the case in which the formula for the macroscopic surface potential is known. Both the differential capacity and the surface potential are treated as unique functions of the potential determining ions (H+ ions). The effects of surface heterogeneity on the surface charge density curves sigma0 = f(pH), and capacity curves c(d) = f(pH), as well as on the position of maximum capacitance are discussed. The "model" effects (influence of the model parameter on the results) are presented.
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