Domain shape relaxation and local viscosity in stratifying foam films
1Laboratoire de Physique des Solides, UMR 8502, Université Paris-Sud, Bât. 510, 91405 Orsay, France. heinig@lps.u-psud.fr
Abstract:
We studied the dynamics of two different types of domain shape relaxation in a stratifying foam film composed of an anionic polymer and cationic surfactant. Those films thin in stepwise fashion: circular domains of lower film thickness are formed, expand and coalesce until they cover the whole film surface. We found that the shape relaxation of coalescing domains is governed only by 2D dissipation, and the measurement of the time scales allows to determine the ratio between the driving force (line tension) and local film viscosity. Further, we analyzed the withdrawal of stripes and modeled it by a moving disc pulled by an external force. Here, 3D dissipation can not be neglected (Stokes paradox) and the equilibrium velocity depends logarithmically on the viscosity of the surrounding 3D air. The evaluation of both kinds of relaxation events yields the orders of magnitude of film viscosity and line tension. For the investigated system we found that the film viscosity is at least 30 times larger than the bulk viscosity, which can be explained by the local molecular ordering and strong interactions with film surfaces.
More Related Videos
10:06Microfluidic Fabrication Techniques for High-Pressure Testing of Microscale Supercritical CO2 Foam Transport in Fractured Unconventional Reservoirs
Published on: July 2, 2020
08:38Microfluidic Devices for Characterizing Pore-scale Event Processes in Porous Media for Oil Recovery Applications
Published on: January 16, 2018
Related Concept Videos
Viscosity of Fluid
Viscosity
Viscosity
The SI unit of viscosity is...
Newtonian Fluid: Problem Solving
A velocity gradient forms within the fluid when a Newtonian fluid is placed between two parallel plates, with...
Molecular Weight of Step-Growth Polymers
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Pressure Variation in a Fluid at Rest
When measuring pressure at two different levels within the fluid, the difference in pressure...
