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Updated: Aug 14, 2026

Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
Published on: February 20, 2020
Gas-phase ion chemistry in organometallic systems
Lorenza Operti1, Roberto Rabezzana
1Dipartimento di Chimica Generale ed Organica Applicata and NIS Centre of Excellence, Università degli Studi di Torino, Corso M. d'Azeglio 48, 10125 Torino, Italy.
Abstract:
This review essentially deals with positive ion/molecule reactions occurring in gas-phase organometallic systems, and encompasses a period of time of approximately 7 years, going from 1997 to early 2004. Following the example of the excellent review by Eller & Schwarz (1991; Chem Rev 91:1121-1177), in the first part, results of reaction of naked ions are presented by grouping them according to the neutral substrate, while in the second part, ligated ions are grouped according to the different ligands. Whenever possible, comparison among similar studies is attempted, and general trends of reactivities are evidenced.
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