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Updated: Aug 14, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Universal power law in the orientational relaxation in thermotropic liquid crystals
Dwaipayan Chakrabarti1, Prasanth P Jose, Suman Chakrabarty
1Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India.
Abstract:
We observe a surprisingly general power law decay at short to intermediate times in orientational relaxation in a variety of model systems (both calamitic and discotic, and also lattice) for thermotropic liquid crystals. As all these systems transit across the isotropic-nematic phase boundary, two power law relaxation regimes, separated by a plateau, emerge, giving rise to a steplike feature (well known in glassy liquids) in the single-particle second-rank orientational time correlation function. In contrast to its probable dynamical origin in supercooled liquids, we show that the power law here can originate from the thermodynamic fluctuations of the orientational order parameter, driven by the rapid growth in the second-rank orientational correlation length.
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