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Updated: Aug 13, 2026
Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
Published on: March 12, 2015
[Study of the characterization of beta-cyclodextrin-acetylferrocene-thiosemicarbazone inclusion complex and
Jing Zhang1, Wan-yi Liu, Xia Zhang
1Key Laboratory of Energy Sources and Engineering, Ningxia University, Yinchuan 750021, China.
Abstract:
Inclusion complex of acetylferrocene-thiosemicarbazone(TAF) with beta-cyclodextrin(beta-CD) has been prepared by using kneading method. Elemental analysis and the solubility determination proved that 1:1 inclusion complex has been formed. Characterization of the inclusion complex was studied by UV, FTIR, and X-ray diffractometry. The association constant was calculated to be 227 L x mol(-1) from the straight portion of the phase-solubility diagram. Furthermore, the influence of different solvents and pH on UV spectrum of acetylferrocene-thiosemicarbazone and beta-CD -TAF was discussed respectively. The results show that different micro-environment has apparently different effects on electric spectra of guest and inclusion complexes.
