Related Experiment Video
Updated: Aug 13, 2026

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
Published on: June 20, 2019
Polyelectrolyte templated polymerization in langmuir films: nanoscopic control of polymer chain organization
M Sharath Chandra1, T P Radhakrishnan
1School of Chemistry, University of Hyderabad, Hyderabad 500046, India.
Abstract:
Polyelectrolytes introduced in the aqueous subphase are shown to have a profound impact on the kinetics of polymerization of N-octadecylaniline at the air/water interface. This can be attributed to changes effected in molecular organization and reorientation behavior in the Langmuir film. The polyelectrolyte templates lead to considerable modification of the morphology of the monomer and polymer Langmuir films. Polyelectrolyte complexation is found to be an elegant and efficient methodology to achieve enhanced alignment of the polyaniline chains in the transferred Langmuir-Blodgett (Langmuir-Schafer) film.
Related Concept Videos
Anionic Chain-Growth Polymerization: Mechanism
Cationic Chain-Growth Polymerization: Mechanism
Ziegler–Natta Chain-Growth Polymerization: Overview
Anionic Chain-Growth Polymerization: Overview
Radical Chain-Growth Polymerization: Chain Branching
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)

