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Published on: February 17, 2017
Synthesis of 1,4-anhydro-D-fructose and 1,4-anhydro-D-tagatose
Gyula Dekany1, Inge Lundt, Andreas J Steiner
1Glycom ApS, Department of Chemistry, Technical University of Denmark (DTU), Building 201, DK-2800 Kgs. Lyngby, Denmark.
Abstract:
1,4-Anhydro-D-fructose and 1,4-anhydro-D-tagatose were prepared from 1,2-O-isopropylidene-D-glucofuranose via the common intermediate 3,5,6-tri-O-benzyl-D-glucitol. The title compounds may be interesting anti-oxidants and feature activities akin to their natural pyranoid counterpart, 1,5-anhydro-D-fructose.
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