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Assembly of nanotubes of poly(4-vinylpyridine) and poly(acrylic acid) through hydrogen bonding

Ying Tian1, Qiang He, Yue Cui

  • 1Beijing National Laboratory for Molecular Sciences, Key Lab of Colloid and Interface Science, Center for Molecular Sciences, Chinese Academy of Sciences, Zhong Guan Cun, Beijing 100080, China.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|April 11, 2006
PubMed

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...