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Related Experiment Videos

N-[1-(Pentafluorophenyl)ethyl]acetamide.

Ilia A Guzei1, Benjamin C Gorske, Helen E Blackwell

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA. iguzei@chem.wisc.edu

Acta Crystallographica. Section C, Crystal Structure Communications
|May 9, 2006
PubMed
Summary
This summary is machine-generated.

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This study details the crystal structure of a novel fluorinated compound (C10H8F5NO). Researchers observed four unique molecules forming hydrogen-bonded pairs and C4 chains in the crystal lattice.

Area of Science:

  • Crystallography
  • Materials Science
  • Organic Chemistry

Background:

  • Understanding the crystal packing of novel organic compounds is crucial for predicting material properties.
  • Fluorinated organic molecules offer unique electronic and physical characteristics.

Purpose of the Study:

  • To elucidate the crystal structure of the title compound, C10H8F5NO.
  • To analyze the intermolecular interactions and packing motifs in the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
  • Analysis of hydrogen bonding and C-C chain formation was performed.

Main Results:

  • The compound C10H8F5NO crystallizes as a racemate.

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  • Four symmetry-independent molecules were identified in the asymmetric unit.
  • These molecules form hydrogen-bonded pairs, which act as building units for C4 chains propagating parallel to the ab plane.

    • Conclusions:

    • The crystal structure reveals a specific arrangement of fluorinated molecules driven by hydrogen bonding.
    • The observed C4 chain motif provides insights into the self-assembly behavior of this compound.