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Updated: Aug 7, 2026

Characterization of Biological Absorption Spectra Spanning the Visible to the Short-Wave Infrared
Published on: January 10, 2025
Absorption spectrum and assignment of the Chappuis band of ozone
S Yu Grebenshchikov1, R Schinke, Z-W Qu
1Max-Planck-Institut für Dynamik und Selbstorganisation, D-37073 Göttingen, Germany. sgreben@gwdg.de
Abstract:
New global diabatic potential energy surfaces of the electronic states 1B1 and 1A2 of ozone and the non-adiabatic coupling surface between them are constructed from electronic structure calculations. These surfaces are used to study the visible photodissociation in the Chappuis band by means of quantum mechanical calculations. The calculated absorption spectrum and its absolute intensity are in good agreement with the experimental results. A vibrational assignment of the diffuse structures in the Chappuis band system is proposed on the basis of the nodal structures of the underlying resonance states.
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