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Updated: Aug 7, 2026

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
Published on: April 28, 2016
Raman spectroscopic investigation of carbon nanowalls
1Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542, Singapore.
Abstract:
Two-dimensional carbon nanowalls (CNWs) were prepared by microwave plasma-enhanced chemical-vapor deposition and scanning electron microscopy was used to observe their morphologies. The Raman observations of different sample orientations and polarizations show that CNWs are well crystallized. Micro-Raman scattering measurements were also carried out with different excitation laser lines (325, 488, 514, 532, and 633 nm). The D band shows a very strong shift of 46.19 cm(-1)eV with excitation laser energy and this has been explained by the double resonance effect. The decreasing intensity ratios IDIG and ID'/IG with increasing laser excitation energy were detected and discussed.
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