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The chemisorption of dibenzo[a,j]coronene on Si(001)-2 x 1

T Suzuki1, D C Sorescu, K D Jordan

  • 1Surface Science Center, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA.

The Journal of Chemical Physics
|June 21, 2006
PubMed

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Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
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Conformation
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