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An infrared nuNH scale for weakly basic anions. Implications for single-molecule acidity and superacidity.

Evgenii S Stoyanov1, Kee-Chan Kim, Christopher A Reed

  • 1Department of Chemistry, University of California, Riverside, CA 92521, USA.

Journal of the American Chemical Society
|June 29, 2006
PubMed
Summary

Tri-n-octylammonium salts reveal anion basicity and acid strength. N-H stretching frequencies correlate with acidity, offering insights into molecular-level acid properties and potential for discovering new superacids.

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