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Dynamics of chloromethanes in cryptophane-E inclusion complexes: a 2H solid-state NMR and X-ray diffraction study

Oleg Petrov1, Zdenek Tosner, Ingeborg Csöregh

  • 1Department of Physical, Inorganic, and Structural Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.

The Journal of Physical Chemistry. A
|July 13, 2006
PubMed
Summary

This study used variable temperature deuterium (2H) solid-state Nuclear Magnetic Resonance (NMR) to investigate guest molecule dynamics within cryptophane-E inclusion complexes. Chloroform showed slow reorientation, while dichloromethane exhibited fast motion, revealing distinct guest dynamics.

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