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Initial crystallization mechanism of isotactic polystyrene from different States

Jianming Zhang1, Yongxin Duan, Harumi Sato

  • 1Department of Chemistry, School of Science and Technology, Research Center for Environment Friendly Polymers, Kwansei-Gakuin University, Gakuen, Sanda 669-1337, Japan.

The Journal of Physical Chemistry. B
|July 21, 2006
PubMed
Summary

Investigating isotactic polystyrene crystallization, this study reveals distinct cold- and melt-crystallization pathways. Differences in kinetics, crystallinity, and spectral changes suggest varied spinodal decomposition origins before polymer crystallization.

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