Product channels of the HCCO + NO reaction
Justin P Meyer1, John F Hershberger
1Department of Chemistry and Molecular Biology, North Dakota State University, Fargo, North Dakota 58105, USA.
Abstract:
The product branching ratio of the HCCO + NO reaction was investigated using the laser photolysis/infrared absorption technique. Ethyl ethynyl ether (C(2)H(5)OCCH) was used as the HCCO radical precursor. Transient infrared detection of CO, CO(2), and HCNO products was used to determine the following branching ratios at 296 K: phi(CO+HCNO) = 0.78 +/- 0.04 and phi(CO(2)+HCN) = 0.22 +/- 0.04. These values are in good agreement with some recent ab initio calculations.
Related Concept Videos
Preparation of Diols and Pinacol Rearrangement
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.
Aldehydes and Ketones with HCN: Cyanohydrin Formation Overview
Phase I Reactions: Oxidation of Carbon-Heteroatom and Miscellaneous Systems
In carbon-nitrogen systems, aliphatic and aromatic amines can undergo oxidative reactions. Secondary and tertiary amines, like those found in tricyclic antidepressants, can undergo N-dealkylation, a process that involves the oxidation of the alkyl group. In addition, oxidative...
Benzene to Phenol via Cumene: Hock Process
Reactions of Carboxylic Acids: Introduction
Aldehydes and Ketones with HCN: Cyanohydrin Formation Mechanism


