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Related Experiment Videos

Hydrogen adsorption on functionalized nanoporous activated carbons.

X B Zhao1, B Xiao, A J Fletcher

  • 1Northern Carbon Research Laboratories, School of Natural Sciences, Bedson Building, University of Newcastle upon Tyne, Newcastle upon Tyne, NE1 7RU, UK.

The Journal of Physical Chemistry. B
|July 21, 2006
PubMed
Summary

Hydrogen storage in porous carbons is temperature-dependent, with optimal adsorption occurring at low temperatures. Functional groups slightly hinder hydrogen uptake, impacting energy applications.

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Area of Science:

  • Materials Science
  • Physical Chemistry
  • Chemical Engineering

Background:

  • Hydrogen adsorption on carbon materials is crucial for energy storage applications.
  • Understanding the influence of carbon properties on hydrogen uptake is vital.

Purpose of the Study:

  • To systematically investigate the impact of functional groups and porous structure on hydrogen adsorption in porous carbons.
  • To determine the thermodynamic properties of hydrogen adsorption and their relation to storage limitations.

Main Methods:

  • Preparation of porous carbons with varying nitrogen and oxygen functional groups.
  • Characterization of porous structures using nitrogen and carbon dioxide adsorption.
  • Measurement of hydrogen adsorption isotherms at 77 K and 100 kPa.

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  • Determination of adsorption enthalpies using virial and van't Hoff equations.
  • Main Results:

    • Hydrogen adsorption isotherms were Type I (IUPAC classification).
    • Adsorption is highly temperature-dependent, with minimal uptake above 195 K.
    • Isosteric enthalpies of adsorption ranged from 3.9-5.2 kJ mol⁻¹.
    • Maximum hydrogen uptake correlated with micropore volume.

    Conclusions:

    • Porous carbon structure, particularly micropore volume, is key for hydrogen adsorption capacity.
    • Functional groups have a minor negative effect on hydrogen adsorption.
    • Thermodynamics indicate significant temperature limitations for practical hydrogen storage.