Laser ablation inductively coupled plasma mass spectrometry assisted insight into ion-selective membranes

Laser ablation inductively coupled plasma mass spectrometry was used to evaluate ion depth profiles across ion-selective membranes. Advantageously, this approach does not require incorporation of additional components (e.g., chromoionophore) in the membrane composition, as compared to that used in typical potentiometric applications. Moreover, comparison of the distribution of ions in differently pretreated membranes is possible. Concentration profiles of primary and interfering agent (Na+) ions were recorded, for example, of Pb2+-selective poly(vinyl chloride)-based membranes. It was found that the contents and the distribution of Pb(2+) and Na+ ions across the membrane is strongly dependent on the composition of the solutions to which both sides of the membrane are exposed during preconditioning and on the plasticizer included in the membrane formulation. Typical plasticizers, bis(2-ethylhexyl sebacate) (DOS) and the more polar 2-nitrophenyl octyl ether (o-NPOE), were used. It was found that faster ion transport occurs for o-NPOE, and the membrane saturation with Pb2+ ions was achieved within less than 20 h for a 400-microm-thick membrane. In the case of the less polar plasticizer DOS, due to slower rate of ion transport, even after 20 h, the Pb2+ concentration gradients were still visible within the membrane. On the basis of concentration profiles, primary ion diffusion coefficients in both membranes were calculated, and the value obtained for o-NPOE containing membrane was found to be approximately 2 times higher than for its DOS-plasticized counterpart.