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Updated: Jul 20, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
4-acetamido-3,3,5,5-[2H4]-2,2,6,6-tetra([2H3]methyl)piperidin-1-yloxyl 0.33-hydrate
Jarmila Duskova1, Jiri Labsky, Ivana Cisarova
1Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovskeho nam. 2, Praha 6, Czech Republic. duskova@imc.cas.cz
Abstract:
The asymmetric unit of the title compound, C11H5D16N2O(2).0.33H2O, is formed by three crystallographically independent piperidin-1-yloxyl molecules and a molecule of water. The molecules are crosslinked by nine hydrogen bonds into layers parallel with the ac plane. The water molecule contributes to the stability of the low-symmetry arrangement by four hydrogen bonds.
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