Diastereoselective synthesis of beta-Aryl-C-nucleosides from 1,2-anhydrosugars
1Humboldt-Universität zu Berlin, Institut für Chemie, Brook-Taylor-Strasse 2, D-12489 Berlin, Germany.
Organic Letters
|September 8, 2006
Abstract:
The cis opening of glycal epoxides with arylaluminum reagents provides strict stereocontrol in C-glycosylation. beta-Aryl-C-2-deoxynucleosides are obtained from known glycals by an epoxidation-glycosylation-deoxygenation sequence.
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