Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

A single-bonded cationic terminal borylene complex.

Dragoslav Vidovic1, Michael Findlater, Gregor Reeske

  • 1Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA.

Chemical Communications (Cambridge, England)
|September 14, 2006
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Synthesis of a Mixed Bis(imino)acenaphthene (BIAN) Ligand Using Aluminum Transfer Reagents.

Molecules (Basel, Switzerland)·2026
Same author

Formation of Cationic Silanols via Hydrolysis of Carbodiphosphorane-Stabilized Trichlorosilane.

Inorganic chemistry·2025
Same author

Preparation of Boron-Nitrogen-Containing Conjugate Polymers via Controlled Hydroboration of Imines.

Inorganic chemistry·2025
Same author

Challenges in Product Selectivity for Electrocatalytic Reduction of Amine-Captured CO<sub>2</sub>: Implications for Reactive Carbon Capture.

ACS omega·2025
Same author

A bespoke water T-maze apparatus and protocol: an optimized, reliable, and repeatable method for screening learning, memory, and executive functioning in laboratory mice.

Frontiers in behavioral neuroscience·2024
Same author

Improved Syntheses of an Arseno-Fatty Acid (As-FA 362) and an Arseno-Hydrocarbon (As-HC 444).

Synthesis·2024
Same journal

A one-step immunoassay of Tau protein based on flow cytometric counting of target-induced nanoaggregates.

Chemical communications (Cambridge, England)·2026
Same journal

Decarboxylative alkylation of unactivated olefins <i>via</i> photoinduced Fe-LMCT: access to alkylated dihydropyrazoles/tetrahydropyridazines.

Chemical communications (Cambridge, England)·2026
Same journal

MOF-ionic liquid engineered polymer electrolyte for advanced solid-state sodium metal batteries.

Chemical communications (Cambridge, England)·2026
Same journal

Chemically-fueled transient peptide hydrogel enabling programmable time-gated functions.

Chemical communications (Cambridge, England)·2026
Same journal

The first structurally characterized coordination compounds with homocysteine.

Chemical communications (Cambridge, England)·2026
Same journal

Bimetallic Bi-In interfaces on micropyramidal silicon for efficient solar-driven CO<sub>2</sub>-to-formate conversion.

Chemical communications (Cambridge, England)·2026
See all related articles

A novel cationic borylene complex featuring iron and boron was synthesized. Structural and computational analyses confirmed a single bond between boron and iron, advancing organometallic chemistry.

Area of Science:

  • Organometallic Chemistry
  • Inorganic Chemistry
  • Computational Chemistry

Background:

  • Organoboron compounds are versatile building blocks in synthesis.
  • Terminal borylene complexes are rare and highly reactive species.
  • Understanding metal-boron bonding is crucial for catalysis and materials science.

Purpose of the Study:

  • To synthesize and characterize a novel cationic terminal borylene complex.
  • To investigate the electronic structure and bonding in the Fe-B interaction.
  • To provide experimental and computational evidence for the nature of the metal-boron bond.

Main Methods:

  • Synthesis of the cationic borylene complex via reaction with aluminum chloride.
  • X-ray crystallography for detailed structural determination.

Related Experiment Videos

  • Spectroscopic analysis (e.g., NMR, IR) for characterization.
  • Density Functional Theory (DFT) calculations for electronic structure and bonding analysis.

    • Main Results:

    • Isolation and full characterization of the cationic terminal borylene complex [(eta5-C5H5)(CO)2FeB(eta5-C5Me5)][AlCl4].
    • X-ray crystallographic data revealed the molecular geometry and coordination environment.
    • Spectroscopic data provided insights into the electronic properties.
    • DFT calculations indicated a bond order of one for the boron-iron bond.

    Conclusions:

    • The synthesized compound is a stable cationic terminal borylene complex.
    • The experimental and computational data unequivocally support a single bond (B-->Fe) between boron and iron.
    • This study contributes to the understanding of low-coordinate boron species stabilized by transition metals.