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Updated: Jul 19, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes
Kortney L Klinkel1, Lauren A Kiemele, Douglas L Gin
1Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado, USA.
Abstract:
Bimetallic complexes based on the binucleating ligand N,N,N',N'-tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane (1L) and its new toluoyl ester derivative (2L) catalyze the hydrolysis of phosphorus triesters at ambient temperature with activities rivalling the fastest known systems.
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