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Updated: Jul 19, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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Counter-ion dynamics in crosslinked poly(styrene sulfonate) systems studied by NMR.

R H Tromp1, J R van der Maarel, J de Bleijser

  • 1Gorlaeus Laboratories, Department of Physical and Macromolecular Chemistry, State University of Leiden, P.O. Box 9502, 2300 RA Leiden, Netherlands.

Biophysical Chemistry
|October 1, 1991
PubMed
Summary

Nuclear magnetic relaxation rates in crosslinked sodium poly(styrene sulfonate) (PSS) ion exchange resins are enhanced due to polymer dynamic constraints. These findings reveal characteristic network length scales related to crosslink density.

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